Pyrolysis characteristics of oil shale semi-coke and its extracted bitumen
نویسندگان
چکیده
Fushun oil shale semi-coke and its extracted bitumen were prepared for analyzing their pyrolysis characteristics by TG–DTG, TG–FTIR, Py–GC/MS. Semi-coke was the residue of pyrolyzed to 450 °C, organic matter from with [Bmim]Cl/NMP mixed solvents. Gaussian fitting method used analyze proportions bond cleavage reactions occured during 700 °C at a heating rate 20 °C/min. Results showed that 3–4 kinds cleavages mainly involved. The outstanding behaviors contributed CalCal weak bonds (including volatilization). kinetic parameters based on Coats–Redfern calculated points each stage reaction. evolution processes typical gaseous products distributions flash displayed in detail, exhibiting prominent roles aliphatic compounds, CH4, CO2. Moreover, releases tended occur higher temperatures.
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ژورنال
عنوان ژورنال: Journal of Analytical and Applied Pyrolysis
سال: 2021
ISSN: ['1873-250X', '0165-2370']
DOI: https://doi.org/10.1016/j.jaap.2021.105120